ie-Physics

Experiment V-2

Another Revolution

Art of Alchemy to the New Chemical Science

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Alchemy was the product of skilled Egyptian artists who carefully guarded their trade secrets for dyeing, painting, glass making, pyrotechnics, medical drugs, mining, and metallurgy.  Despite the secrecy, it was nurtured in the Museion in Alexandria and gradually developed in the tolerance of the Moslem culture.  The ritualized processes for calcination, sublimation, condensation, crystallization, albification, solidifcation, and transformation involved the incantations of mysticism as much as the vocabulary of Greek elements.

Arab physicians such as Rhazes and Avicenna codified and recorded the medicine of Alchemy in the 10th and 11th Centuries in reference texts that became the standards for centuries.

Alchemy was brought back to Europe by returning Crusaders perhaps largely for its medical benefits.  (Presumably the return of the Crusaders was as wildly celebrated as that of today's crusaders. [ ...as ships and aircraft return from the Iraq war of liberation, as this was being drafted, 5/6/2003 dwt]  Despite the intent of the Crusades to spread Christianity to others, the Crusades changed the homelands more than it changed the middle east!  Perhaps that will be true again?)  In the 16th century the physician Paracelsus wandered widely through Europe, spreading his version of alchemy with little concern for secrecy.  Once alchemy became the interest of Europeans who did not need to maintain secrecy to protect their livelihood, experimentation and the sharing of findings resulted in alchemy rapidly growing beyond its theoretical foundations.

Robert BoyleDuring medieval times, air gained the reputation as an elusive, unknowable element.  (Our term gas derived as a varied pronunciation of chaos, which was Greek for unknowable.)  But the development of the technique of collecting airs by displacing liquids such as water and mercury from full containers immersed upside down in larger containers resulted in the production and study of numerous gases with distinct, reproducible properties.  Carefully weighing and comparing initial reactants and final products often caused changes in weights that alchemy could not explain.  While some people such as Robert Boyle (←portrait at left) called for the development of a new chemistry to replace the inadequate alchemy, others such as Johannes Joachim Becker and Georg Ernst Stahl attempted to modify alchemy.  In the end Antoine Lavoisier and other French friends proposed a new chemistry based on a radical new concept of element.  They adopted a proposal offered a century earlier by Boyle: An element is any substance that cannot be separated into several different materials.  Weight change during a chemical reaction would indicated whether a substance was separating or combining.  According to Lavoisier, solids, liquids and gases were actually just three states of existence which most materials would successively exhibit at increasing temperature and could be reversed by cooling.

LaviosierLavoisier (shown right with wife Marie→), realizing the importance of vocabulary for developing and perpetuating ideas, proposed new terms supporting the new chemistry.  For example, to avoid the old term fire conjuring implications of alchemy, Lavoisier substituted the new term caloric.  His book Elements of Chemistry was translated to many languages and widely read.  The superiority of his explanations were apparent and formed the foundation for much new research.

Experiment

Alchemy adopted the Greek view that all gases were essentially the SAME element, air, perhaps each carrying small impurity amounts of other elements.  But with the development of the technique of collecting gases by displacing liquid from an inverted container, very distinct properties seemed to suggest that each gas was actually a DIFFERENT substance.  This interpretation supported the radical new view of the material world proposed by Laviosier.

Baking soda (NaHCO3) and vinegar (HCH3COO) react when mixed to form a gas.  An enzyme in meat promotes the decomposition of hydrogen peroxide (H2O2), making a gas.  And aluminum foil (Al) reacts in water with lye (NaOH) to make a gas.  In this experiment we will compare the properties of the gases produced these three different ways.

You will needdisplacement First Gas Second Gas Third Gas

Procedure

First Gas
  1. Fill the collection container full of water and place it open mouth down in the partially filled water container.  If the water container is large enough, it may be easiest to fill the collection container in the water container, then invert it under water.
  2. Put a couple cm3 of baking soda into a deflated rubber balloon.
  3. Add 10 to 20 cm3 of vinegar and immediately close the neck of the balloon with your fingers.
  4. Place the mouth of the balloon under the collection container, allowing the gas as it is generated to displace the water.
  5. When collection is complete or the collector is full, still wearing goggles, test the gas with a match to determine if the gas is
    1. flammable (causing a small bang),
    2. supports combustion (the flame briefly burns brighter), or
    3. extinguishes combustion (the flame immediately goes out).
    (Hint: You can cover the mouth of a partially filled connection container, perhaps with your hand, then invert it.  Remove cover just before testing.)
Second Gas
  1. Fill the collection container full of water and place it open mouth down in the partially filled water container.
  2. Add 20 to 30 cm3 of hydrogen peroxide into a deflated rubber balloon.  (Avoid touching this liquid.)
  3. Put a couple small pieces of uncooked meat and immediately close the neck of the balloon with your fingers.
  4. Place the mouth of the balloon under the collection container, allowing the gas as it is generated to displace the water.
  5. When collection is complete or the collector is full, still wearing goggles, test the gas with a match to determine if the gas is
    1. flammable,
    2. supports combustion, or
    3. extinguishes combustion.
Third Gas
  1. Fill the collection container full of water and place it open mouth down in the partially filled water container.
  2. Put a couple cm3 of lye and several short rolled strips of Aluminum into a deflated rubber balloon.  (Avoid touching the lye with your fingers.)
  3. Add a few cm3 of water and immediately close the neck of the balloon with your fingers.
  4. Place the mouth of the balloon under the collection container, allowing the gas as it is generated to displace the water.
  5. When collection is complete or the collector is full, still wearing goggles, test the gas with a match to determine if the gas is
    1. flammable,
    2. supports combustion, or
    3. extinguishes combustion.
Do the properties of the gases seem to support the Greek idea that the gases are essentially the same, or Laviosier's idea that each gas is a different substance?

Optional Experiment Extension

  1. Measure the amount of each gas produced.
  2. Repeat steps 1 through 4, varying the proportions of the reactants by using different amounts of ONE reactant.
  3. Graph the amount of gas verses the varied reactant.
  4. Determine the optimum proportions for making the gas.
Try to formulate one or more rules that seem to apply to optimum proportions for these reactions.

Finally, record your procedures, measurements, and findings in your journal.  If you need course credit, use your observations recorded in your journal to construct a formal report

References

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created 5 May 2003
revised 19 January 2007
by D Trapp
Mac made